Small Bag or Mini-Tackle Box for Whatnots: Every officer I know has one and it contains a variety of needful things. Small stapler, knife, lumber crayon (accidents), paper clips, extra flashlight bulb, lip balm, antacids, comb, nail clippers, quantity of "headache helper" (tablets or powders), extra "damits" for uniform, extra pen or pencil. All the little things of life you will need to make you happy in a bind. I have seen toilet paper, rubber bands, waterless sanitizing gel, wet wipes, eye-glass cleaner pads, multipliers or multi-function knives (either or both are a must). Throw a few extra adhesive bandages of smaller sizes to cover up nicks and cuts on your hands and to repel contamination. Other niceties of life could be an extra set of handcuffs, a few flexible plastic cuffs for special events, and a roll of 100 mph tape (duct tape). Did I mention extra ammo? Get a few boxes that are departmental exacts.
Good Quality Sunglasses: There are two schools of thought here. Some believe you will lose them or scratch them up, so go cheap. Others have found that quality optics will offer you better UV protection and will not distort your vision. I go with quality ones because they also make you look more professional. You may even want glasses that offer ballistic protection such as the many varieties made by Wiley-X.
Inclement Weather Bag or Pouch: If you have a rotational fleet then I strongly recommend you have in your POV trunk or locker a bag with the following items. You should have a raincoat, hat cover, gloves (cold weather types), a knit cap or cold weather head cover, and a towel to dry off with. If you are issued a vehicle just keep them in the back.
Secondary Weapon: Before you purchase one, visit your departmental rangemaster and get his or her recommendations. Note: Your department may have guidelines regarding secondary weapons.